By Claudio Morterra, Adriano Zecchnia, Giacomi Costa

ISBN-10: 0444874658

ISBN-13: 9780444874658

Among the world referred to as floor technology (which often bargains with unmarried crystal surfaces) and the colossal region of the skin houses of dispersed solids (knowledge of that is extensively utilized in catalysis and fabrics technological know-how) there's nonetheless a remarkably broad, even if progressively lowering, hole. simply because primary physico-chemical difficulties are concerned, this borderline sector has to be explored. With this goal, the Trieste assembly introduced jointly experts with quite a few origins and backgrounds, with the purpose of stimulating the expansion of our wisdom during this sector. This lawsuits quantity comprises ninety-three papers, comprising plenary lectures, brief communications, and poster contributions at the purposes of actual and theoretical the way to excellent and dispersed (microcrystalline and amorphous) metals, oxides, and combined structures. unique emphasis is given to metal-support interfaces. The booklet hence presents a wealth of up to date details on a subject matter of present curiosity in order to be of worth to researchers who use chemical and/or actual equipment for the examine of surfaces.

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Extra resources for Structure and Reactivity of Surfaces: Proceedings of a European Conference, Trieste, Italy, September 13-16, 1988

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The spectra of pure aminoacids in the solid state, of some of their metal salts and of aminoacid hydrochlorides were also recorded for the purpose of comparison with the data obtained. 1. A section of the cell employed. A: KBr windows,B: quartz tube, C: silica-alumina disc, D: heating coil, E: thermocouple, F:aminoacid container, G vacuum attachment. 1 N to neutralization and then slowly evaporated until the salt precipitated.. 11 the frequencies of the bands observed in the spectra of pure aminoacids, their hydrochlorides and salts in the region 2000-1200 cm-1 are reported together with the assignments known from the literature (9,17,18,24).

White, J. Am. Chem. , 106 (1984) 3059-3060. E. L. Haller, J. , 82 (1983) 279-288. 12 J. Santos, J. A. Dumesic, J. , 81 (1983) 147-167. W. Chung, G. C. Kao, J. , 85 (1984) 237-243. A. S. J. Gorte, J. Phys. , 89 (1985) 1151-1154. E. Levin, M. T. A. Somorjai, J. Chem. , Faraday Trans. I, 83 (1987) 2061-2069. 16 E. Guglielminotti, G. Spoto and A. , 161 (1985) 202-220. C. Fuggle and N. Martensson, J. , 21 (1980) 275-281. E. H. Weinberg, J. Chem. , 70 (1979) 1437-1439. 19 G. E. -I. M. White, Appl. S.

The effects of decorating metal surfaces by TiO, moieties have been studied using metal foils and single crystals (refs. 13-15). However, the nature of the titanium species which migrates (metallic or oxidized) and the type of bonding which exists between this species and the group Vm metal remain as unresolved issues. We report here on the modelling of such systems by investigating TiO, species adsorbed onto the basal plane of ruthenium, and the effect of these moieties on the chemisorptive behaviour of H2 and CO.

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Structure and Reactivity of Surfaces: Proceedings of a European Conference, Trieste, Italy, September 13-16, 1988 by Claudio Morterra, Adriano Zecchnia, Giacomi Costa


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