By James H. Clark, Craig W. Jones

ISBN-10: 0854045368

ISBN-13: 9780854045365

"Simple, yet superbly versatile". probably no longer an outline many would select for hydrogen peroxide, yet a correct one none the fewer, and this particular publication explains the explanations in the back of the outline. starting with an historic review, and guidance for the secure dealing with of peroxygens, functions of Hydrogen Peroxide and Derivatives is going directly to hide key activation mechanisms, natural useful workforce oxidations and using hydrogen peroxide with heterogeneous catalysts. The clean-up of environmental pollution; chemical purification; and extraction of metals from their ores also are mentioned intimately, utilizing real examples from undefined. the flexibility of this reagent might end up to be a key to built-in pollutants regulate sooner or later. This publication should still consequently be learn via teachers and industrialists in any respect degrees, to motivate wider purposes of using hydrogen peroxide in laboratories.

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Extra info for Applications of Hydrogen Peroxide and Derivatives

Example text

Faraday Soc, (a) 1955, 51, 1690; (b) 1956,52,824. R. A. Levy, J. Chem. , 1965, 42, 3054. 45 G. M. B. Ticknor, / . Am. Chem. Soc, 1952, 74, 3715. 46 Gmelins 'Handbuch der Anorganischen Chemie', 8 Auflage, Sauerstoff, Lieferung 7, System-Number 3, Verlag Chemie, 1966. 47 J. MacKenzie, in 'Plant/Operations Progress', 1991, 10, 164. , 'Concentrated Hydrogen Peroxide', Summary of Research Data on Safety Limitations, 1961. , 'Explosion Protection Seminar', January 1986. 50 Schumb, Satterfield and Wentworth, in 'Hydrogen Peroxide', Reinhold Publishing, 1955.

18. 3 H. Meidinger, Ann. Chem. , 1853, 88, 57. 4 H. Berthelot, CR. Hebd. Seances Acad. ScL, 1878, 86, 71. M. Weigart, H. Delle and G. , 1975, 99, 101. 6 W. Manchot, Liebigs Ann. , (a) 1901, 314, 377; (b) 1901, 316, 331. W. Filson, J. Am. Chem. Soc, 1932, 54, 3228. 8 BASF, DRP 649234; Pfleiderer, DRP 6583767. 9 Chemical Econonmics Handbook, 1997. 10 Degussa DE, 1273499. 11 BASFDE, 801840. 12 Degussa, DE 1542089. , GB 718306. , GB 718307. , US 3009782. A. Williams, Chem. Ind. (London), 1959, 76. , US 3902347.

Examples of catalysts known to be particularly effective in this area include platinum, platinum black, silver, cobalt or reduced palladium (either as gauzes or on supports), and the active manganese ore, pyrolusite. These systems are particularly unique in their high activity in acidic solutions. The major drawback with heterogeneous decomposition catalysts is their propensity to lose activity in the presence of oils, inorganic phosphates, colloidal tin and silica complexes, etc. Similarly, highly acidic liquors or those containing strong chelating agents tend to leach the catalysts from their supports.

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Applications of Hydrogen Peroxide and Derivatives by James H. Clark, Craig W. Jones


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